PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

            \(MgO+2HCl\rightarrow MgCl_2+H_2O\)

a) Ta có: \(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)=n_{Mg}\)

\(\Rightarrow\%m_{Mg}=\dfrac{0,5\cdot24}{16}=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)

b) Ta có: \(\left\{{}\begin{matrix}n_{Mg}=0,5\left(mol\right)\\n_{MgO}=\dfrac{16\cdot25\%}{40}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl}=2n_{Mg}+2n_{MgO}=1,2\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{1,2\cdot36,5}{20\%}=219\left(g\right)\)

c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{H_2}=0,5\left(mol\right)\\n_{MgCl_2}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{H_2}=0,5\cdot2=1\left(g\right)\\m_{MgCl_2}=0,6\cdot95=57\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{hhA}+m_{ddHCl}-m_{H_2}=234\left(g\right)\) \(\Rightarrow C\%_{MgCl_2}=\dfrac{57}{234}\cdot100\%\approx24,36\%\)

PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Theo PT: \(n_{Zn}=n_{H_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Zn}=0,2.65=13\left(g\right)\)

\(m_{ZnO}=21,1-13=8,1\left(g\right)\)

Có: \(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)

Theo PT: \(n_{HCl}=2n_{Zn}+2n_{ZnO}=0,6\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\Rightarrow C\%_{ddHCl}=\dfrac{21,9}{200}.100\%=10,95\%\)

Theo PT: \(n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,3\left(mol\right)\)

\(\Rightarrow m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)

Bạn tham khảo nhé!

CcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCcccccccccccccccccccccCccccccccccccccccccccc​

$a\big)$

$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$

$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$

Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$

$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$

$\to \%m_{ZnO}=100-61,61=38,39\%$

$b\big)$

$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$

Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$

$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

 0,2                                                                0,2     ( mol )

\(m_{Zn}=0,2.65=13g\)

\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)

\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)

\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

0,2               0,4                                                  ( mol )

\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)

\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)

 0,1              0,2                                                        ( mol )

\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)

2Al + 6HCl -> 2AlCl₃ + 3H₂ (1)

ZnO + 2HCl -> ZnCl₂ + H₂O (2)

a) n_H2= 13,44/22.4=0.6(mol) -> mH2=0,6.2=1,2(g)

Theo PTHH: n_Al = 2/3 n_H2 = 2/3 . 0,6= 0,4(mol) -> m_Al = 0,4 . 27=10,8(g)

-> m_ZnO = 27-10,8= 16,2(g)

b) n_ZnO = 16,2/81=0,2(mol)

Theo PTHH (2): nHCl = 2nZnO=2.0,2=0,4(mol)

Theo PTHH (1) : nHCl=2nH₂=2.0,6=1,2(mol)

-> \(\Sigma\)nHCl = 0,4+1,2=1,6(mol)

-> mHCl = 1,6.36,5= 58,4(g)

-> mdd_HCl = 58,4.100/29,2= 200(g)

c) Theo PTHH (1): nAlCl₃ = 2/3 nH₂ = 2/3 . 0,6=0,4(mol)                                         -> mAlCl3=0,4.133,5=53,4(g)

mdd sau phản ứng= m_A + mddHCl - mH2 =27+200-1,2 =225,8(g)

-> C% AlCl3 = 53,4.100%/225,8 = 20,88%

Theo PTHH (2) nZnCl2 =nZnO= 0,2(mol)-> mZnCl2=0,2.136=27,2(g)

-> C% ZnCl2= 27,2.100%/255,8=10,63%

Gọi \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo pt: \(\Rightarrow\left\{{}\begin{matrix}3x+y=0,2\\27x+56y=5,5\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=\dfrac{19}{470}\\y=\dfrac{37}{470}\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{5,5}\cdot100\%=19,84\%\)

\(\%m_{Fe}=100\%-19,84\%=80,16\%\)

a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

                   a_____2a______a_____a      (mol)

                \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

                    b_____3b_______b_____\(\dfrac{3}{2}\)b         (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)

b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)

a) Gọi số mol Zn, Fe là a, b (mol)

=> 65a + 56b = 8,56 (1)

\(n_{H_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

           a--->2a-------->a----->a

            Fe + 2HCl --> FeCl₂ + H₂

           b----->2b------->b------>b

=> a + b = 0,14 (2)

(1)(2) => a = 0,08; b = 0,06 

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,08.65}{8,56}.100\%=60,748\%\\\%m_{Fe}=\dfrac{0,06.56}{8,56}.100\%=39,252\%\end{matrix}\right.\)

b) 

n_KOH = 0,2.0,1 = 0,02 (mol)

PTHH: KOH + HCl --> KCl + H₂O

           0,02-->0,02

=> n_HCl = 0,02 + 2a + 2b = 0,3 (mol)

=> \(C_{M\left(HCl\right)}=xM=\dfrac{0,3}{0,15}=2M\)

c) m = 0,08.136 + 0,06.127 = 18,5(g)